Adamite

Zinc arsenate hydroxide mineral
(repeating unit)Zn2AsO4OHIMA symbolAd[1]Strunz classification8.BB.30Dana classification41.06.06.03
Olivenite groupCrystal systemOrthorhombicCrystal classDipyramidal (mmm)
H–M symbol: (2/m 2/m 2/m)Space groupPnnmIdentificationColorPale yellow, honey-yellow, brownish yellow, reddish; rarely white, colorless, blue, pale green to green, may be zonedCrystal habitWedge-like prisms typically in druses and radiating clusters; also smooth botryoidal massesCleavage{101}, good; {010}, poorFractureUneven to subconchoidalTenacityBrittleMohs scale hardness3.5LusterVitreousStreakWhite to pale greenSpecific gravity4.32–4.48 measuredOptical propertiesBiaxial (+/−)Refractive indexnα=1.708 – 1.722, nβ=1.742 – 1.744, nγ=1.763 – 1.773Birefringenceδ = 0.055Other characteristicsMay fluoresce and phosphoresce lemon-yellow under SW and LW UV.References[2][3][4]

Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.

Adamite on limonite from the Gold Hill District Tooele County, Utah, US. Scale at bottom is c. 2.5 cm.

Occurrence

Adamite occurs as a secondary mineral in the oxidized zone of zinc- and arsenic-bearing hydrothermal mineral deposits. It occurs in association with smithsonite, hemimorphite, scorodite, olivenite, calcite, quartz and iron and manganese oxides.[2]

The yellow to bright lime-green colored crystals and druze along with its distinctive fluorescence make adamite a favorite among mineral collectors. Found in Mapimí, Durango, Mexico; Greece; and California and Utah in the United States.

Adamite was named after the French mineralogist Gilbert-Joseph Adam (1795–1881). It was first described in 1866 for an occurrence at the type locality of Chañarcillo, Copiapó Province, Atacama Region, Chile.[3]

See also

References

  1. ^ Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b http://rruff.geo.arizona.edu/doclib/hom/adamite.pdf Handbook of Mineralogy
  3. ^ a b http://www.mindat.org/min-21.html Mindat.org
  4. ^ http://webmineral.com/data/Adamite.shtml Webmineral data
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Wikisource has the text of the 1920 Encyclopedia Americana article Adamite.