Tridecane
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Preferred IUPAC name Tridecane[1] | |
Identifiers | |
CAS Number |
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3D model (JSmol) |
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Beilstein Reference | 1733089 |
ChEBI |
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ChEMBL |
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ChemSpider |
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ECHA InfoCard | 100.010.086 |
EC Number |
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KEGG |
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MeSH | tridecane |
PubChem CID |
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RTECS number |
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UNII |
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CompTox Dashboard (EPA) |
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InChI
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Properties | |
Chemical formula | C13H28 |
Molar mass | 184.367 g·mol−1 |
Appearance | Colourless liquid |
Odor | Gasoline-like to odorless |
Density | 0.756 g mL−1 |
Melting point | −6 to −4 °C; 21 to 25 °F; 267 to 269 K |
Boiling point | 232 to 236 °C; 449 to 457 °F; 505 to 509 K |
log P | 7.331 |
Vapor pressure | 100 kPa (at 59.4 °C) |
Henry's law constant (kH) | 4.3 nmol Pa−1 kg−1 |
Refractive index (nD) | 1.425 |
Thermochemistry | |
Heat capacity (C) | 406.89 J K−1 mol−1 |
Std enthalpy of formation (ΔfH⦵298) | −379.3–−376.1 kJ mol−1 |
Std enthalpy of combustion (ΔcH⦵298) | −8.7411–−8.7383 MJ mol−1 |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P305+P351+P338 | |
Flash point | 94 °C (201 °F; 367 K) |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 1.161 g kg−1 (intravenous, mouse) |
Related compounds | |
Related alkanes | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references |
Chemical compound
Tridecane or n-tridecane is an alkane with the chemical formula CH3(CH2)11CH3. Tridecane is a combustible colourless liquid. In industry, they have no specific value aside from being components of various fuels and solvents. In the research laboratory, tridecane is also used as a distillation chaser.
Natural occurrence
Nymphs of the southern green shield bug produce tridecane as a dispersion/aggregation pheromone, which possibly serves as a defense against predators.[2] It is also the main component of the defensive fluid produced by the stink bug Cosmopepla bimaculata.[3]
See also
References
- ^ "tridecane – Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification. Retrieved 4 January 2012.
- ^ Todd, J. W. (1989). "Ecology and behavior of Nezara viridula". Annual Review of Entomology. 34: 273–292(20). doi:10.1146/annurev.en.34.010189.001421.
- ^ Krall, Brian S.; Bartelt, Robert J.; Lewis, Cara J.; Whitman, Douglas W. (1999). "Chemical Defense in the Stink Bug Cosmopepla bimaculata". Journal of Chemical Ecology. 25 (11): 2477–94(18). doi:10.1023/A:1020822107806. S2CID 13652977.
External links
- Material Safety Data Sheet for Tridecane
- Phytochemical and Ethnobotanical Databases
- v
- t
- e
- Methane (CH4)
- Ethane (C2H6)
- Propane (C3H8)
- Butane (C4H10)
- Pentane (C5H12)
- Hexane (C6H14)
- Heptane (C7H16)
- Octane (C8H18)
- Nonane (C9H20)
- Decane (C10H22)
- Undecane (C11H24)
- Dodecane (C12H26)
- Tridecane (C13H28)
- Tetradecane (C14H30)
- Pentadecane (C15H32)
- Hexadecane / Cetane (C16H34)
- Heptadecane (C17H36)
- Octadecane (C18H38)
- Nonadecane (C19H40)
- Icosane (C20H42)
- Heneicosane (C21H44)
- Tetracosane (C24H50)
- Nonacosane (C29H60)
- Hentriacontane (C31H64)