Vanadiocarpholite

(repeating unit)Mn+2V+3AlSi2O6(OH)4IMA symbolVcar[1]Strunz classification9.DB.05Crystal systemOrthorhombicCrystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)Space groupCccaUnit cella = 13.83 Å, b = 20.681 Å
c = 5.188 Å; Z = 8IdentificationColorPale-straw yellow, honey-yellow to brownCrystal habitPrismatic to acicular crystal clusters, vein fillingsCleavagePerfect on {010}TenacityFlexibleLusterVitreous, silkyDiaphaneityTransparentOptical propertiesBiaxial (+)Refractive indexnα=1.684, nβ=1.691, nγ=1.7Birefringence0.0160References[2][3]

Vanadiocarpholite (Mn+2V+3AlSi2O6(OH)4) is straw yellow to brown silicate mineral. It crystallizes in the orthorhombic crystal system. It is the vanadium rich variety of carpholite (Mn+2Al2Si2O6(OH)4).

Discovery and occurrence

It was first described in 2005 for an occurrence in the Molinello Mine, Graveglia Valley, Genova Province, Liguria, Italy.[3] It occurs in chert in a manganese ore deposit as vein fillings in silicified wood.[2]

Chemical composition

It consists of:[2]

Manganese 15.56% Mn 20.09% MnO
Aluminium 7.64% Al 14.44% Al2O3
Vanadium 14.43% V 21.23% V2O3
Silicon 15.91% Si 34.04% SiO2
Hydrogen 1.14% H 10.21% H2O
Oxygen 45.32% O

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Vanadiocarpholite data on Webmineral.com
  3. ^ a b Vanadiocarpholite on Mindat.org


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